(1) Thermal Resistance
PBT (Polybutylene Terephthalate): Melting point ~225℃, limited long-term use below 120℃.
PPS (Polyphenylene Sulfide): Melting point 290℃, HDT 260℃, suitable for 180–220℃ continuous service.
(2) Flame Retardancy
PBT: Slow-burning (UL94 HB).
PPS: Self-extinguishing (UL94 V-0), oxygen index 44%, ideal for fire-safe applications.
(3) Molding Performance
PBT: High shrinkage (1.5–2.2%), requires post-mold sizing.
PPS: Low shrinkage (0.2–0.8%), excellent dimensional stability.
(4) Water Absorption
PBT: 0.07–0.09%, needs pre-drying.
PPS: 0.03%, minimal humidity impact.
Advantages:
Balanced mechanical strength, low friction, and wear resistance.
Good electrical insulation (except high-frequency loss).
Resistant to oils, alkalis, and weak acids.
Limitations:
Notch-sensitive, poor impact strength (requires FR-PBT).
Poor hydrolysis resistance.
Advantages:
Extreme Heat Resistance: Stable at 200–240℃ long-term.
Chemical Inertness: Resists most solvents (except strong oxidizers).
High Stiffness: Tensile strength up to 137MPa (GF-reinforced).
Flame Retardant: Meets aerospace/automotive standards.
Limitations:
Brittleness (modified grades like R-4/G-6 are common).
High cost (~2–3× PBT).
PBT:
Low-cost electronics (connectors, switches).
Automotive non-critical parts.
PPS:
High-temperature capacitors, IC trays.
Aggressive chemical environments.
Conclusion:
PPS excels in high-end applications demanding heat/flame resistance, while PBT offers cost-effective solutions for general-purpose uses. Material selection depends on temperature, budget, and precision requirements.
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